Pokemon Blue Episode 2: Rival Battle 2, Catching Pikachu and Challenging Brock for the Boulder Badge

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Rival Battle 2 on Route 22

Rival's Pokemon:

1) Pidgey Lv. 9
Gust
Sand Attack
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2) Starter (Bulbasaur, Charmander or Squirtle) Lv. 8 
Bulbasaur                      Charmander             Squirtle
Tackle                              Scratch                    Tackle
Growl                               Growl                       Tail Whip
Leech Seed                                                      Bubble

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Catching Pikachu in Viridian Forest

Pokemon in Viridian Forest and Encounter Rate (Blue Only)
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Caterpie (Bug): 50%
Lv. 3 - Lv. 5

Metapod (Bug): 35%
Lv. 4 - Lv. 6

Weedle (Bug, Poison): 5%
Lv. 3

Kakuna (Bug, Poison): 5%
Lv. 4
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Pikachu (Electric): 5%
Lv. 3 - Lv. 5

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Battling Brock for the Boulder Badge

Pewter City Gym Trainers (Blue, Green and Red Only)

Jr. Trainer
Diglett (Ground) Lv. 11: Scratch
Sandshrew (Ground) Lv. 11: Scratch, Sand Attack

Gym Leader Brock
Geodude (Rock, Ground) Lv. 12: Tackle, Defense Curl
Onix (Rock, Ground) Lv. 14: Tackle, Screech, Bide